Chapter 4 · ApplicationsRedox all around us

Applications & Explore Online റിഡോക്സ് പ്രവർത്തനങ്ങൾ

Redox reactions are not only in the laboratory. The iron gate rusting in the salty sea breeze, the firewood in the kitchen hearth, your breathing after a football match, the banana leaves rotting in the compost pit, the torch battery, the bleaching powder in the village well, the iron in a bicycle and the silver in an old photograph: in every one of them some atoms lose electrons and others gain them. Every section has a small animation and a sample exam question. The page ends with a hub of links to explore online.

📖 The ideas behind every section

Parts marked go further are beyond the textbook. Enjoy them, but for the exam stick to the textbook ideas. The animations are simplified.

🔩 Rustinggates, boats, GI sheets 🔥 Combustionfirewood, biogas, LPG ⚽ Respirationenergy after a match 🍂 Compostdecomposition in oxygen 🔋 Batterieselectrochemical cells 💧 Bleachdisinfecting a well 🏭 Iron from orereduction with carbon 📷 Silverphotographs

1. Rusting of iron gates and fishing boats, and how to stop it

Near the coast, iron gates, window grills, bicycle chains and the iron parts of fishing boats turn reddish-brown and flaky very quickly. This is rusting. Iron combines with oxygen from the air in the presence of moisture; salt in the sea breeze makes it faster. Each iron atom loses electrons (oxidation) and each oxygen atom gains them (reduction): rusting is a redox reaction that forms an oxide layer ഓക്സൈഡ് ആവരണം. The textbook equation is 4Fe + 3O₂ → 2Fe₂O₃. To stop it, we keep air and water away: paint on gates, oil or grease on chains and tools, and a coat of zinc on galvanised iron (GI) sheets for roofs. go further Real rust also contains water (hydrated iron oxide); zinc protects even where the coat is scratched, because zinc is oxidised in place of the iron.

🌊 One monsoon by the sea
Bare iron: oxygen and moisture reach the metal. Fe loses electrons, O gains them. Rust spreads.
4{0|Fe} + 3{0|O}₂ → 2{+3|Fe}₂{−2|O}₃Fe: 0 → +3 (oxidised) · O: 0 → −2 (reduced) · in Fe₂O₃: 2x + 3(−2) = 0 → x = +3
📝 In the exam this looks like… “Iron gates near the sea rust quickly. (a) Rusting is called a redox reaction. Why? (b) Find the oxidation number of iron in Fe₂O₃. (c) Suggest two ways to prevent rusting.”
(a) In 4Fe + 3O₂ → 2Fe₂O₃, iron loses electrons, its oxidation number rising from 0 to +3 (oxidation), while oxygen gains electrons, falling from 0 to −2 (reduction). Both happen together, so it is redox. (b) 2x + 3 × (−2) = 0 → x = +3. (c) Any two: painting, oiling or greasing, galvanising (coating with zinc); all keep oxygen and moisture away from the iron.

2. Firewood in the hearth, biogas and LPG: combustion

When firewood burns in the kitchen hearth അടുപ്പ്, its carbon combines with oxygen of the air and gives out heat and light. Burning, or combustion ജ്വലനം, is a redox reaction. Take carbon (charcoal) as the fuel: C + O₂ → CO₂. Carbon goes from 0 to +4 (oxidised; it is the reducing agent); oxygen goes from 0 to −2 (reduced; it is the oxidising agent), exactly as in Table 4.9. Methane, the main gas in biogas plants, burns the same way: CH₄ + 2O₂ → CO₂ + 2H₂O. The LPG in the cooking cylinder (mainly butane and propane) also burns to carbon dioxide and water. go further The wood seems to lose mass only because the CO₂ and water vapour fly away (page 3).

🔥 Light the fuel
Firewood (carbon): C + O₂ → CO₂. C 0 → +4 (oxidised), O 0 → −2 (reduced).
{0|C} + {0|O}₂ → {+4|C}{−2|O}₂carbon: reducing agent · oxygen: oxidising agent
📝 In the exam this looks like… “Methane in biogas burns as CH₄ + 2O₂ → CO₂ + 2H₂O. (a) Find the oxidation number of carbon before and after the reaction. (b) Is this a redox reaction? Name the oxidising agent.”
(a) In CH₄: x + 4(+1) = 0 → C = −4. In CO₂: x + 2(−2) = 0 → C = +4. (b) Yes. {−4|C}{+1|H}₄ + 2{0|O}₂ → {+4|C}{−2|O}₂ + 2{+1|H}₂{−2|O}. Carbon rises from −4 to +4 (oxidation) while oxygen falls from 0 to −2 (reduction) at the same time. The oxidising agent is O₂; the reducing agent is CH₄.
⚠ If you smell LPG in the kitchen: do not light a match or switch on any light or fan, close the cylinder regulator, open the doors and windows, go out and tell an adult. Never play with fire, and keep children away from the hearth and the stove.

3. Respiration: where the energy for a football match comes from

After a football match you breathe fast and deep. Your muscles need energy, and they get it from respiration ശ്വസനം: in the cells, glucose from food is broken down with the oxygen you breathe in, giving carbon dioxide, water and energy. Lavoisier showed that respiration takes in oxygen and gives out carbon dioxide, like a slow burning. It is a redox reaction: the carbon of glucose is oxidised and the oxygen is reduced. go further The overall equation is C₆H₁₂O₆ + 6O₂ → 6CO₂ + 6H₂O + energy. In glucose the average oxidation number of carbon is 0 (6x + 12 − 12 = 0); in CO₂ it is +4.

⚽ Play, breathe, release energy
More effort → more glucose oxidised each second → more oxygen needed → you breathe faster.
📝 In the exam this looks like… “Respiration is said to be a redox reaction. Explain. Which substance acts as the oxidising agent?”
In respiration glucose is broken down using oxygen to give carbon dioxide, water and energy. The carbon of glucose ends up in CO₂ with a higher oxidation number (it is oxidised), and oxygen, 0 in O₂, becomes −2 in H₂O and CO₂ (it is reduced). Oxidation and reduction happen together, so it is redox. Oxygen is the oxidising agent.

4. Banana leaves in the compost pit: decomposition in oxygen

Banana leaves, vegetable peels and dry leaves thrown into a compost pit slowly turn into dark, crumbly manure. Tiny living things, bacteria and fungi, decompose വിഘടനം the organic matter, using oxygen from the air. The carbon is oxidised to carbon dioxide, and heat is given out (a good compost heap feels warm inside). That is why farmers turn the heap now and then: it lets air in. Decomposition of organic matter in oxygen is one of the redox reactions named in the textbook. go further A cut apple or banana going brown is also an oxidation by the oxygen of air, helped by substances in the fruit; lemon juice slows it down.

🍂 Watch the heap over the weeks
📝 In the exam this looks like… “Why is it advised to turn a compost heap regularly? Which type of chemical reaction takes place in it?”
Turning lets air (oxygen) into the heap. The microbes use oxygen to decompose the organic matter into carbon dioxide, water and heat; the carbon is oxidised and the oxygen is reduced. It is a redox reaction (decomposition of organic matter in oxygen).

5. Torch and mobile batteries: electricity from redox

A torch cell (dry cell) and a mobile phone battery are electrochemical cells രാസവൈദ്യുത സെല്ലുകൾ. Inside, a redox reaction is split into two halves at two different places. In a dry cell the zinc case is oxidised, Zn → Zn²⁺ + 2e⁻; the electrons cannot jump straight across, so they travel through the wire and the bulb to the carbon rod, where another substance (manganese dioxide) is reduced. That flow of electrons is the electric current. go further In a mobile phone's lithium-ion battery, lithium atoms give up electrons while the phone is used: Li → Li⁺ + e⁻; charging pushes the reaction back.

🔋 Close the switch
Switch off: the electrons have no path, so no reaction and no light.
📝 In the exam this looks like… “In a dry cell, the zinc case changes into zinc ions (Zn²⁺). (a) Write the equation for this change. (b) Is zinc oxidised or reduced? Why?”
(a) Zn → Zn²⁺ + 2e⁻. (b) Zinc is oxidised: it loses electrons and its oxidation number increases from 0 to +2. (Like other metals, zinc tends to lose electrons.)
⚠ Never open, cut, burn or heat a battery, never join its two ends with a wire or a coin (short circuit), and stop using a phone battery that is swollen or hot. Put used cells in an e-waste collection box, not in the fire or the compost pit.

6. Bleaching powder in the well: oxidising agents that kill germs

After a flood, or before the monsoon, health workers add a measured amount of bleaching powder to wells. It releases chlorine, which acts as an oxidising agent ഓക്സീകാരി: it takes electrons from the substances in germs and in coloured stains, destroying them. While it oxidises them, the chlorine itself is reduced to chloride ions: Cl + 1e⁻ → Cl⁻ (oxidation number 0 → −1). Purple potassium permanganate (KMnO₄) is another strong oxidising agent used to disinfect; its manganese has oxidation number +7 (page 7) and is reduced when it reacts. Bleaching of cloth and paper also works by oxidation.

💧 Treat the well water
Chlorine takes electrons from the germs: the germs are oxidised (destroyed), chlorine is reduced to Cl⁻.
📝 In the exam this looks like… “Chlorine is used to disinfect drinking water because it is an oxidising agent. (a) What happens to chlorine itself in the reaction? (b) Write the change of chlorine as an equation.”
(a) An oxidising agent is itself reduced: chlorine gains electrons and its oxidation number falls from 0 to −1. (b) Cl + 1e⁻ → Cl⁻ (or Cl₂ + 2e⁻ → 2Cl⁻).
⚠ Bleaching powder and KMnO₄ are added to wells only by trained health workers, in the right amount. Never mix bleach with acids, toilet cleaners or other cleaning liquids: poisonous chlorine gas is given off. Keep these chemicals away from eyes, skin and children.

7. Getting iron from its ore: reduction with carbon go further

Iron is found in the earth as an ore, mainly iron oxide (Fe₂O₃), with iron at +3. To get the metal, the iron ions must gain electrons: the ore must be reduced. In a blast furnace the ore is heated strongly with coke (carbon). Carbon takes away the oxygen and is itself oxidised: 2Fe₂O₃ + 3C → 4Fe + 3CO₂. Here carbon is the reducing agent നിരോക്സീകാരി. (In the real furnace much of the work is done by carbon monoxide, CO, made from the coke.) Rusting and extraction are the same change run in opposite directions: rusting oxidises iron to its oxide, the furnace reduces the oxide back to iron.

🏭 Inside a blast furnace (simplified)
Fe +3 → 0 (reduced, gains electrons); C 0 → +4 (oxidised): carbon is the reducing agent.
2{+3|Fe}₂{−2|O}₃ + 3{0|C} → 4{0|Fe} + 3{+4|C}{−2|O}₂check: Fe 4 = 4 · O 6 = 6 · C 3 = 3
📝 In the exam this looks like… “2Fe₂O₃ + 3C → 4Fe + 3CO₂. (a) Which substance is reduced? (b) Which is the reducing agent? Give reasons using oxidation numbers.”
(a) Fe₂O₃ is reduced: iron's oxidation number falls from +3 to 0. (b) Carbon is the reducing agent: its oxidation number rises from 0 to +4 (it is oxidised and brings about the reduction of iron oxide). O stays −2.

8. Silver in old photographs go further

Before digital cameras, black-and-white photographs were made on film coated with a silver compound containing silver ions, Ag⁺. Where light fell on the film, and then in the developer solution, the silver ions gained electrons and became tiny grains of black silver metal: Ag⁺ + e⁻ → Ag. This is exactly the example in the textbook of a positive ion being reduced. The bright parts of the scene became dark on the film (a “negative”). Silver ornaments slowly going dull and dark is the opposite change: silver reacting with sulphur compounds in the air, an oxidation.

📷 Expose and develop the film
Ag⁺ + e⁻ → Ag: each silver ion gains an electron (reduction) and becomes a black grain of silver.
📝 In the exam this looks like… “Ag⁺ + e⁻ → Ag. Is this oxidation or reduction? What is the change in the oxidation number of silver?”
Reduction: the silver ion gains an electron. The oxidation number of silver decreases from +1 to 0.
🔑 One idea, many uses

Something loses electrons, something gains them. Metals lose electrons when they rust or power a battery (Fe → Fe³⁺, Zn → Zn²⁺). Oxygen gains electrons when fuels burn, food is respired and leaves decompose. Oxidising agents such as chlorine and KMnO₄ kill germs and are reduced. Reducing agents such as carbon get metals back from their ores. Write the oxidation numbers above the symbols and the story is always the same: up = oxidation, down = reduction.

🌐 Explore online – resources hub

Everything in this guide works offline. The links below are extras: a simulation and articles from trusted sources (PhET, Wikipedia), grouped by topic. They need internet and open in a new tab, so you will not lose your place here. Ask a parent or teacher before you go online. The PhET simulations run directly in the browser, with nothing to install.

Conservation of mass and Lavoisier

🌐 Conservation of mass and Lavoisier needs internet · opens in a new tab

Balancing chemical equations

🌐 Balancing chemical equations needs internet · opens in a new tab

Oxidation, reduction and redox

🌐 Oxidation, reduction and redox needs internet · opens in a new tab

Oxidation number

🌐 Oxidation number needs internet · opens in a new tab

Redox reactions in daily life

🌐 Redox reactions in daily life needs internet · opens in a new tab

More to explore

🌐 More to explore needs internet · opens in a new tab
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