Chapter 5 · ApplicationsReaction rates all around us

Applications & Explore Online രാസപ്രവർത്തനവേഗം

Controlling the rate of a reaction is everyday work. We slow reactions down when we keep fish in ice, salt mangoes for pickle or paint an iron gate before the monsoon. We speed them up when we split firewood, leave the dosa batter out overnight, chew our rice well, or let a catalyst make ammonia for fertilisers. Every section below has a small animation, the factor at work, and a sample exam question. The page ends with a hub of links to explore online.

📖 The ideas behind every section

The blue tag at the start of each section names the factor at work. Parts marked go further are beyond the textbook; numbers marked illustrative are rough. The animations are simplified.

🐟 Food preservationice, salt, pickles, drying 🫓 Batter & curdwarm days ferment faster 🍲 Pressure cookerhotter water, faster cooking 🪵 Firewoodsplit it small 🎆 Fireworksmagnesium powder 🚗 Air bags0.03 s of chemistry 🚙 Catalytic convertercleaner exhaust 😋 Saliva & ricean enzyme at work 🏭 Ammonia & fertiliserHaber process 🛤️ Rail weldingthermite 🔩 Rust preventionslowing a slow reaction

1. Fish in ice, salted fish and mango pickle: slowing decay

temperature · water · air Fish, milk and cooked rice spoil because of chemical reactions: microbes and their enzymes break the food down, and oils react with the oxygen of the air and go rancid. Food preservation പ്രിസർവേറ്റീവുകൾ means slowing these reactions down. Fish sellers pack fish in ice and we keep food in the refrigerator: at a low temperature the particles have less kinetic energy, fewer reach the threshold energy, and decay is slow. Salting fish, making mango pickle with salt and vinegar, drying in the sun and storing in sugar syrup take away the water microbes need. Vacuum packing keeps oxygen away. Permitted preservatives are chemicals that slow spoiling.

🐟 How long does the fish stay fresh?
Kitchen shelf at 30 °C: warm, moist and in air, so the decay reactions are fast.

illustrative times Real times depend on the fish and on hygiene.

📝 In the exam this looks like… “Fish sellers keep fish covered with ice. (a) Which factor affecting the rate of reaction is used here? (b) Explain using collision theory. (c) Write two other ways of preserving food.”
(a) Temperature (low temperature). (b) At a low temperature the particles have less kinetic energy, so fewer particles reach the threshold energy; there are fewer effective collisions and the reactions that spoil the fish become slower. (c) Any two: salting, drying in the sun, pickling in vinegar or salt, storing in sugar syrup, vacuum packing, adding permitted preservatives, refrigeration.

2. Dosa batter and curd: warm days ferment faster

temperature Grind rice and urad dal at night and by morning the batter has risen and smells sour. This fermentation is a chemical change done by the enzymes എൻസൈമുകൾ of yeast and bacteria; the bubbles are carbon dioxide. In the summer the batter rises in a few hours; on a cold rainy night it takes much longer; in the fridge it hardly changes. Curd sets the same way: warm milk with a spoon of curd sets by morning, and we put the curd in the fridge to slow further souring. go further Too much heat (above about 45 °C) kills the microbes, so the batter is kept warm, never hot.

🫓 Overnight batter
📝 In the exam this looks like… “Idli batter ferments faster in summer than in the rainy season. (a) Name the factor that affects the rate here. (b) Why do we keep set curd in the refrigerator?”
(a) Temperature. At the higher temperature the particles have more kinetic energy, more reach the threshold energy, there are more effective collisions, and fermentation (carried out by enzymes of microbes) is faster. (b) The low temperature slows down the reactions that make curd more and more sour, so it stays good for longer.

3. Pressure cooker: hotter water cooks faster go further

temperature Cooking rice, dal or meat is a set of chemical changes in starch and proteins. In an open pot the water cannot get hotter than its boiling point, 100 °C. In a pressure cooker the steam is trapped, the pressure rises, and the water boils at about 120 °C. At the higher temperature the cooking reactions are much faster, so dal that takes about an hour in an open pot is ready in a few whistles. At hill stations like Munnar water boils a little below 100 °C, so cooking in an open pot is slower there.

🍲 Open pot vs pressure cooker

illustrative times

📝 In the exam this looks like… “Food cooks faster in a pressure cooker than in an open vessel. Which factor that affects the rate of reaction is involved? Explain.”
Temperature. Inside the cooker the water boils at a higher temperature (about 120 °C instead of 100 °C). The particles have more kinetic energy, more of them reach the threshold energy, and the effective collisions increase, so the chemical changes of cooking take place faster.
⚠ Never block or remove the weight or safety valve of a pressure cooker, never fill it more than about two-thirds, and open it only after all the pressure has gone. Let an adult handle it.

4. Split firewood and kindling

surface area A thick log is hard to light and burns slowly; the same wood split into small pieces catches fire easily and burns fast; thin dry twigs and coconut husk (kindling) flare up at once. Burning is a reaction between wood and the oxygen of the air, and it can happen only at the surface of the wood. Splitting the wood increases the surface area പ്രതലപരപ്പളവ്, so more oxygen particles collide with the wood every second. Fanning the fire or blowing through a pipe adds more oxygen (concentration).

🪵 Same mass of wood, three ways
📝 In the exam this looks like… “Firewood split into small pieces burns faster than a big log of the same mass. Explain on the basis of collision theory.”
Small pieces have a much larger surface area. Burning takes place at the surface, so more oxygen particles collide with the wood per second, giving more effective collisions and a higher rate of burning.

5. Vishu and Onam fireworks: magnesium powder

surface area A magnesium ribbon burns steadily with a dazzling white flame. In fireworks, magnesium (and aluminium) are used as a fine powder: its huge surface area lets the metal react with oxygen almost at once, giving a brilliant flash. The same idea explains why fine coal dust in mines and flour dust in mills can explode go further.

✨ Ribbon vs powder
📝 In the exam this looks like… “Magnesium is used in fireworks in the form of a powder, not a ribbon. Why?”
Powder has a much greater surface area than a ribbon of the same mass. More magnesium particles are exposed to oxygen, there are more effective collisions, and the magnesium burns very fast, giving a brilliant flash.
⚠ Fireworks are dangerous. Only adults should light them, outdoors, with a bucket of water or sand nearby, standing well back. Never make, open or handle firework powder, never hold a lit cracker, and never go back to one that did not go off. Keep pets and small children away.

6. Car air bags: a decomposition in 0.03 s

a very fast reaction In a crash, a sensor sends an electric spark into a small charge of sodium azide. It decomposes at once: 2NaN₃ → 2Na + 3N₂↑. The nitrogen gas fills the nylon bag in about 0.03 s, faster than a blink, so the bag is ready before the person is thrown forward. This is a decomposition reaction വിഘടന രാസപ്രവർത്തനം, and here the high rate is exactly what saves lives. go further Other chemicals in the unit make the reactive sodium harmless.

🚗 The first 60 milliseconds of a crash
2NaN₃ → 2Na + 3N₂↑one compound → two substances: decomposition · about 0.03 s
📝 In the exam this looks like… “In an air bag, sodium azide changes as 2NaN₃ → 2Na + 3N₂. (a) Which type of reaction is this? (b) Why must this reaction be very fast?”
(a) Decomposition reaction: one compound breaks into two substances. (b) The bag must fill with nitrogen in a fraction of a second (about 0.03 s), before the passenger is thrown forward; a slow reaction would be useless.
⚠ An air bag works together with the seat belt, not instead of it. Small children should sit in the back seat in a proper child seat, never in front of an air bag.

7. Catalytic converters in vehicles go further

catalyst Car and bike exhaust contains poisonous carbon monoxide (CO), nitrogen oxides (NO) and unburnt fuel. In the exhaust pipe of modern vehicles sits a catalytic converter: a honeycomb coated with tiny amounts of the metals platinum, palladium and rhodium. On their huge surface the harmful gases are changed quickly into carbon dioxide, nitrogen and water. The metals are catalysts ഉൽപ്രേരകം: they are not used up, so one converter works for years. The honeycomb shape gives a large surface area too.

🚙 Through the honeycomb
2CO + O₂ → 2CO₂  ·  2CO + 2NO → 2CO₂ + N₂on the surface of Pt / Pd / Rh catalysts
📝 In the exam this looks like… “Platinum and rhodium in a catalytic converter are not used up even after years of use. What is the role of these metals? What is a catalyst?”
They act as catalysts: they increase the rate at which CO, NO and unburnt fuel change into CO₂, N₂ and H₂O. A catalyst is a substance that increases the rate of a reaction without itself undergoing a permanent chemical change, which is why the metals last for years.

8. Chew your rice: amylase in saliva

enzyme (catalyst) · surface area Keep a mouthful of rice in your mouth and chew it for a minute: it starts to taste sweet. Saliva contains the enzyme amylase, a biological catalyst that speeds up the breakdown of starch into the sugar maltose. Chewing well breaks the food into small bits (more surface area for the enzyme), and our body temperature, about 37 °C, suits the enzyme. Without enzymes, digestion would take far too long for life. Enzymes in nature even power the hot spray of the bombardier beetle, which decomposes hydrogen peroxide very fast (textbook box).

😋 Amylase cuts starch into maltose
starch  —amylase→  maltosethe enzyme is a catalyst: it comes out unchanged and works again
📝 In the exam this looks like… “Rice chewed for a long time tastes sweet. (a) Name the enzyme responsible. (b) What are enzymes? (c) Why is it good to chew food well?”
(a) Amylase in saliva (starch → maltose, a sweet sugar). (b) Enzymes are biological catalysts: they increase the rate of reactions in living things without being used up. (c) Chewing breaks food into small pieces, which increases the surface area, so digestion is faster.

9. Ammonia for fertilisers: the Haber process

catalyst · temperature · pressure Ammonia is made from nitrogen (from the air) and hydrogen by the Haber process ഹേബർ പ്രക്രിയ: N₂(g) + 3H₂(g) ⇌ 2NH₃(g). At room temperature the reaction is far too slow to be useful. Industry uses iron (Fe) as the catalyst, a pressure of about 200 atm and a temperature of about 700 K. The sign ⇌ means the reaction is reversible ഉഭയദിശാ പ്രവർത്തനങ്ങൾ, so the unreacted gases are sent round again. Ammonia is turned into fertilisers such as ammonium sulphate and urea; in Kerala, fertiliser factories such as FACT at Udyogamandal make ammonia-based fertilisers. In the contact process സമ്പർക്ക പ്രക്രിയ for sulphuric acid, 2SO₂(g) + O₂(g) ⇌ 2SO₃(g) is speeded up by vanadium pentoxide (V₂O₅) at about 2 atm and 720 K.

🏭 Inside an ammonia plant (simplified)
📝 In the exam this looks like… “N₂(g) + 3H₂(g) ⇌ 2NH₃(g). (a) Name this industrial process. (b) Which catalyst is used? (c) What does the sign ⇌ show? (d) Which catalyst is used in the contact process?”
(a) Haber process (manufacture of ammonia). (b) Iron (Fe), at about 200 atm and 700 K. (c) The reaction is reversible: it can go in both directions. (d) Vanadium pentoxide (V₂O₅).

10. Welding railway lines with thermite

a very fast displacement Long welded rails make the train ride smooth. To join two rails, workers place a mould around the gap and set off a thermite തെർമൈറ്റ് mixture of aluminium powder and iron oxide in a crucible above it: Fe₂O₃ + 2Al → 2Fe + Al₂O₃. Aluminium displaces iron from its oxide (a displacement reaction ആദേശ രാസപ്രവർത്തനം). Once started, the reaction is so fast and gives out so much heat that the iron formed is molten; it runs down into the gap and welds the rails together. The fine powders help it go fast.

🛤️ Molten iron fills the gap
📝 In the exam this looks like… “Fe₂O₃ + 2Al → 2Fe + Al₂O₃ is used to weld railway tracks. (a) Name the type of reaction. (b) Which element is displaced? (c) Why is the iron obtained in the molten state?”
(a) Displacement reaction (the thermite reaction). (b) Iron is displaced by aluminium. (c) The reaction is very fast and gives out a very large amount of heat, enough to melt the iron formed, which then flows into the gap.
⚠ The thermite reaction reaches temperatures above 2000 °C and throws out sparks of molten metal. It is done only by trained railway crews with protective clothing. Never try it.

11. Rust prevention: slowing down a slow reaction

contact · moisture Rusting തുരുമ്പിക്കൽ of iron is slow, but over months it eats gates, bicycles and tin roofs. It needs both oxygen and water to reach the iron surface, so it is fastest in our humid monsoon, and near the sea, where salt speeds it up further. We slow it by stopping those collisions: painting gates and grills, oiling or greasing chains and tools, galvanising (a zinc coat, as on GI sheets), and keeping tools dry.

🔩 One monsoon on an iron grill
📝 In the exam this looks like… “Iron gates rust faster during the monsoon. (a) Why? (b) Suggest two methods to slow down rusting.”
(a) Rusting needs both water and oxygen at the iron surface. In the monsoon there is much more moisture, so more effective collisions take place at the surface and rusting is faster. (b) Any two: painting, oiling or greasing, galvanising (coating with zinc), keeping the iron dry; each stops water and oxygen from reaching the iron.
🔑 One idea, many uses

Rate depends on effective collisions. To slow a reaction: cool it (fridge, ice), remove a reactant (salt or dry away the water, vacuum-pack away the oxygen) or block contact (paint, oil). To speed it up: warm it (summer batter, pressure cooker), increase the surface area (split firewood, magnesium powder, chewing) or use a catalyst (iron in the Haber process, V₂O₅ in the contact process, platinum in a converter, amylase in saliva).

🌐 Explore online – resources hub

Everything in this guide works offline. The links below are extras: a simulation and articles from trusted sources, grouped by topic. They need internet and open in a new tab, so you will not lose your place here. Ask a parent or teacher before you go online.

Types of chemical reactions

🌐 Types of chemical reactions needs internet · opens in a new tab

Rate of reaction

🌐 Rate of reaction needs internet · opens in a new tab

Collision theory and threshold energy

🌐 Collision theory and threshold energy needs internet · opens in a new tab

Catalysts and enzymes

🌐 Catalysts and enzymes needs internet · opens in a new tab

More to explore

🌐 More to explore needs internet · opens in a new tab
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