Chapter 8 · ApplicationsHydrocarbons all around us

Applications & Explore Online കാർബണിക രസതന്ത്രം

Hydrocarbons cook our food, move our autorickshaws, light our lamps, smooth our roads and keep moths out of our clothes. Every section below has a small animation or diagram, the chemistry at work and a sample exam question. Safety boxes cover the fuels (all flammable) and moth balls (toxic). The last section is about climate change in Kerala and what each of us can do. The page ends with a hub of links to explore online.

📖 The ideas behind every section

The blue tag at the start of each section names the idea at work. Parts marked go further are beyond the textbook; pictures marked illustrative show a trend, not measured values.

🔥 LPG cylinderbutane 🛺 CNG autosmethane, GAIL pipeline ⛽ Petrol & dieselchain length decides 🪔 Kerosene lampC₁₀–C₁₆ 🕯️ Vaseline & candleslong chains 🛣️ Tarred roadsbitumen 🧦 Moth ballsnaphthalene – careful! 🧴 Plastics & medicinesfrom petroleum 🏭 Coal powerwhy we cut it 🌧️ Kerala's climatewhat we can do

1. LPG cooking gas: butane in the kitchen

butane C₄H₁₀ · alkane · burns The red cylinder in a Kerala kitchen holds LPG എൽ.പി.ജി, liquefied petroleum gas. Its main component is butane ബ്യൂട്ടെയ്ൻ, C4H10, an alkane with 4 carbons, from the “gases” fraction (C1–C4) of petroleum. Under pressure inside the cylinder it is a liquid, so a lot of fuel fits in a small space. When you turn the knob, the pressure drops and the liquid turns to gas, flows to the stove and burns with a hot blue flame. go further 2C4H10 + 13O2 → 8CO2 + 10H2O + heat.

🔥 Open the regulator, light the stove
📝 In the exam this looks like… “Butane, the main component of LPG, is an alkane with 4 carbon atoms. (a) Write its molecular formula. (b) Write its condensed formula. (c) To which fraction of petroleum does it belong?”
(a) n = 4: H = 2 × 4 + 2 = 10 → C4H10. (b) CH3–CH2–CH2–CH3. (c) The gases fraction, C1–C4, used as domestic and industrial fuel (Table 8.9).
⚠ LPG is highly flammable. If you smell gas (a strong smell is added on purpose so leaks are noticed): do not switch on any light, fan or mobile phone near it, do not light a match; turn off the regulator, open doors and windows, go outside and tell an adult, who can call the LPG emergency number 1906. Never play with the stove or the cylinder.

2. CNG autorickshaws and the LNG pipeline

natural gas = mainly methane CH₄ Natural gas പ്രകൃതിവാതകം is mostly methane, CH4, the first alkane. Squeezed into strong cylinders at high pressure it becomes CNG സി.എൻ.ജി, compressed natural gas, which runs many autorickshaws and buses in Kochi. Turned into a liquid it is LNG എൽ.എൻ.ജി, liquefied natural gas, which takes up far less space and can be carried by ship. LNG arrives at the terminal at Puthuvype, Kochi, and GAIL supplies it as gas through pipelines in Kerala, to factories, CNG stations and kitchens (piped gas). Methane has only one carbon, so burning it gives less carbon pollution (less CO2 and soot for the same heat): it is the more eco-friendly fuel. go further In practice LNG is made by cooling the gas to about −162 °C; CH4 + 2O2 → CO2 + 2H2O.

🛺 Natural gas → CNG → LNG illustrative
📝 In the exam this looks like… “(a) Expand CNG and LNG. (b) What is the main component of natural gas? (c) Why is CNG called an eco-friendly fuel?”
(a) CNG – compressed natural gas; LNG – liquefied natural gas. (b) Methane, CH4. (c) It burns almost completely and causes less carbon pollution (less CO2, smoke and soot) than petrol or diesel.
⚠ CNG cylinders hold gas at very high pressure. Only trained mechanics fill or repair them; no smoking or flames at a CNG station.

3. Petrol, diesel and the length of the chain

number of carbons → properties of the fuel At the petrol pump you can buy petrol (C5–C10) or diesel (C16–C20). They come from different heights of the same fractionating tower ഫ്രാക്ഷണേറ്റിങ് ടവർ at a refinery such as BPCL's Kochi refinery. Short chains boil at low temperatures and catch fire easily, so petrol suits the spark engines of scooters and cars; the longer diesel chains suit the diesel engines of buses, lorries and many autos. Your textbook's key idea: the number of carbon atoms and the structure of the chain decide the properties of a fuel. Slide along the chain to meet every fraction of Table 8.9.

⛓️ Fraction finder – how many carbons?
📝 In the exam this looks like… “Some fractions of petroleum are given: petrol, diesel, bitumen, kerosene. (a) Which has the fewest carbon atoms? (b) Which is used for tarring roads? (c) What decides the properties of a fuel?”
(a) Petrol (C5–C10). (b) Bitumen (above C70). (c) The number of carbon atoms and the structure of the carbon chain.
⚠ Petrol and diesel vapours catch fire very easily. Never play near fuel cans, never siphon fuel by mouth, and switch off engines and phones at the petrol pump.

4. Kerosene lamps

kerosene C₁₀–C₁₆ · domestic fuel Kerosene മണ്ണെണ്ണ (C10–C16) was the fuel of the chimney lamp and the wick stove in almost every Kerala home, and is still used during power cuts and by fishing boats. The cloth wick soaks up kerosene; the flame's heat turns it to vapour, and the vapour burns. Kerosene does not catch fire as easily as petrol, which is why it could be used in open lamps; with too little air it burns with a sooty, smoky flame.

🪔 Light the lamp
📝 In the exam this looks like… “Kerosene and diesel are both fractions of petroleum. (a) Give the number of carbons in each. (b) Write one use of each.”
(a) Kerosene C10–C16; diesel C16–C20. (b) Kerosene – domestic fuel (lamps, stoves); diesel – fuel for diesel engines.
⚠ Kerosene burns: keep lamps away from curtains and children, never refill a lit lamp, and never use kerosene to start a fire.

5. Vaseline, grease and candles: the long chains

long chains → thick, waxy, high boiling Lower down the tower come chains too long to boil easily. Petroleum jelly (vaseline) and grease, C20–C50, are used as lubricants in bicycle chains and machines, and in cosmetics such as lip balm and skin cream. Paraffin wax (C60–C70 in Table 8.9) makes candles, boot polish, wax paper and tarpaulin. In a candle, the solid wax melts, the liquid wax climbs the wick, turns to vapour and burns – the same idea as the kerosene lamp, with a solid fuel.

🕯️ How a candle burns
📝 In the exam this looks like… “Match each fraction with its use: (i) petroleum jelly (ii) paraffin wax (iii) naphtha — candles / lubricant and cosmetics / fuel in thermal power stations.”
(i) Petroleum jelly – lubricant and cosmetics; (ii) paraffin wax – candles (also boot polish, wax paper, tarpaulin); (iii) naphtha – fuel in thermal power stations.

6. Tarred roads: bitumen

bitumen – above C₇₀ The black, sticky residue left at the very bottom of the fractionating tower is bitumen (more than 70 carbons per molecule). Heated until it flows, it is mixed with crushed stone and spread on the road, then pressed by a road roller; as it cools it sets hard and binds the stones and keeps water out. That is the “tar” of our roads.

🛣️ Lay a road
📝 In the exam this looks like… “Which petroleum fraction has the largest number of carbon atoms? Write its use.”
Bitumen (above C70) – used for tarring roads.

7. Moth balls: naphthalene

naphthalene C₁₀H₈ · aromatic The white balls kept in cupboards and with stored clothes are moth balls പാറ്റാഗുളിക. Many are made of naphthalene നാഫ്തലീൻ, C10H8: two benzene rings fused together, an aromatic hydrocarbon with a strong smell that keeps moths and insects away. It is obtained from coal tar. Over weeks the balls get smaller without leaving any liquid: the solid turns straight into vapour (it sublimes go further), which is why their smell fills the cupboard.

🧦 A moth ball in the cupboard illustrative
📝 In the exam this looks like… “Moth balls are made of an aromatic hydrocarbon. (a) Name it. (b) Write its molecular formula. (c) Draw its structure.”
(a) Naphthalene. (b) C10H8. (c) Two benzene rings fused side by side, with alternating double bonds (the drawing above).
⚠ Naphthalene is toxic. Keep moth balls away from children – they look like sweets – and never taste, chew or play with them. Keep them in closed cupboards, not near food, and wash your hands after handling them. Benzene is also toxic.

8. Plastics and medicines from petroleum go further

petrochemicals Not all petroleum is burnt. Small molecules such as ethene, CH2=CH2, made from petroleum fractions, are the starting materials for plastics. When the double bonds of thousands of ethene molecules open, the molecules join end to end into one very long chain: polythene, used for carry bags, milk packets and bottles. Benzene and other compounds from petroleum and coal tar are used to make medicines, dyes, perfumes and synthetic fibres. Because plastics are made to last, throwing them away pollutes our land and sea: reduce, reuse and recycle.

🧴 Ethene molecules join into polythene
📝 In the exam this looks like… “Ethene is the raw material of polythene. (a) Write the molecular formula of ethene. (b) To which family does it belong? (c) Write its general formula.”
(a) C2H4 (CH2=CH2). (b) Alkenes – it has a C=C double bond. (c) CnH2n.

9. Coal in power stations – and why we burn less of it

coal: carbonisation · % carbon Coal കൽക്കരി formed from plants buried millions of years ago: heat and pressure, without air, slowly turned them into carbon – carbonisation കാർബണൈസേഷൻ. The longer and harder the process, the more carbon: peat 57 %, lignite 67 %, bituminous coal 83 %, anthracite 94 %. Much of India's electricity still comes from thermal power stations that burn coal: C + O2 → CO2. Every tonne of carbon burnt adds carbon dioxide to the air, along with smoke and ash. That is why the country is adding solar, wind and hydro power, and why saving electricity at home also cuts CO2.

🏭 The coal ladder – tap a type
📝 In the exam this looks like… “(a) What is carbonisation? (b) Arrange peat, anthracite, lignite and bituminous coal in increasing order of carbon content. (c) Why should we reduce the burning of coal?”
(a) The slow change of buried plant remains into carbon at high temperature and pressure in the absence of air. (b) Peat < lignite < bituminous < anthracite (57 %, 67 %, 83 %, 94 %). (c) Burning coal gives CO2, a greenhouse gas that causes global warming, and pollutes the air; coal is also a fossil fuel that will run out.

10. Climate change in Kerala – and what we can do

greenhouse gases trap infrared rays Sunlight warms the Earth; the warm Earth sends out infrared rays ഇൻഫ്രാറെഡ് രശ്മികൾ. CO2, CH4, N2O and CFCs (the greenhouse gases ഹരിതഗൃഹവാതകങ്ങൾ) trap part of this heat. A little of this greenhouse effect ഹരിതഗൃഹപ്രഭാവം keeps Earth warm enough for life; the extra gases from burning fossil fuels and cutting forests trap more, and the average temperature rises: global warming. Kerala already feels it: the extreme rain and floods of August 2018, more very hot days, and the sea eating into the coast. The good news: each of us can help.

🌍 More greenhouse gas, more heat kept in illustrative

✅ My climate actions – tick what you will do this month:

📝 In the exam this looks like… “(a) Name two greenhouse gases. (b) What is the greenhouse effect? (c) Write two ways to reduce global warming.”
(a) Any two: CO2, CH4, N2O, CFCs. (b) Greenhouse gases in the atmosphere trap part of the infrared rays given out by the Earth's surface and keep the Earth warm. (c) Any two: burn less fossil fuel; use solar and wind energy; plant trees and protect forests; use public transport or CNG/electric vehicles; save electricity; use CFC-free appliances.
⚠️ Safety summary
🔑 One chapter, many uses

Butane C4H10 – LPG. Methane CH4 – natural gas, CNG, LNG (less carbon pollution). Petroleum fractions (Table 8.9): gases C1–C4, petrol C5–C10, naphtha C8–C12, kerosene C10–C16, diesel C16–C20, jelly/grease C20–C50, fuel oil C50–C70, paraffin wax C60–C70, bitumen > C70. Naphthalene C10H8 – moth balls. Ethene – polythene. Coal: peat → lignite → bituminous → anthracite. Greenhouse gases CO2, CH4, N2O, CFCs → global warming.

🌐 Explore online – resources hub

Everything in this guide works offline. The links below are extras: articles and simulations from trusted sources, grouped by topic. They need internet and open in a new tab, so you will not lose your place here. Ask a parent or teacher before you go online.

Organic chemistry and catenation

🌐 Organic chemistry and catenation needs internet · opens in a new tab

Hydrocarbons: alkanes, alkenes, alkynes

🌐 Hydrocarbons: alkanes, alkenes, alkynes needs internet · opens in a new tab

IUPAC naming

🌐 IUPAC naming needs internet · opens in a new tab

Ring compounds and aromatic hydrocarbons

🌐 Ring compounds and aromatic hydrocarbons needs internet · opens in a new tab

Petroleum, coal and natural gas

🌐 Petroleum, coal and natural gas needs internet · opens in a new tab

Greenhouse effect and global warming

🌐 Greenhouse effect and global warming needs internet · opens in a new tab
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