Answer Key – Set 1 ഉത്തരസൂചിക
Step-by-step answers and the marking scheme for every question of Set 1, for teachers and parents to value the paper. Accept any correct answer in the student’s own words; give method marks even when the final number is wrong.
Step-by-step solution
- If the α particles met nothing on their way, there must be nothing in most of the atom to stop or turn them. So most of the atom is empty space (ഗോൾഡ് ഫോയിൽ പരീക്ഷണം).
- The positive nucleus (a) was concluded from the few particles that were deflected or bounced back; (c) is Bohr’s idea; (d) is Thomson’s plum pudding model.
Marking: 1 mark for (b).
📖 Revise: Ch 1 · Gold foil experiment · Chapter 1 – Structure of the Atom
Step-by-step solution
- The atom gives away its 2 outermost electrons: Mg → Mg2+ + 2e−.
- The number of electrons (12 → 10), the charge (0 → +2) and the configuration (2, 8, 2 → 2, 8) all change. Only electrons move; the nucleus is untouched, so the number of protons stays 12.
Marking: 1 mark for (b).
📖 Revise: Ch 3 · Table 3.6 – Mg before and after · Chapter 3 – Chemical Bonding
Step-by-step solution
- This is the definition of ionisation energy (അയോണീകരണ ഊർജം), also called ionisation enthalpy.
Marking: 1 mark.
📖 Revise: Ch 3 · Ionisation energy · Chapter 3 – Chemical Bonding
Step-by-step solution
- Sodium atoms lose electrons: Na → Na+ + e− (oxidation number 0 → +1). Sodium is oxidised.
- Oxygen atoms gain electrons: O + 2e− → O2− (0 → −2). Gain of electrons is reduction (നിരോക്സീകരണം), so oxygen is reduced.
Marking: 1 mark for (b).
📖 Revise: Ch 4 · Oxidising and reducing agents · Chapter 4 – Redox Reactions
Step-by-step solution
- By the law of conservation of mass (മാസ് സംരക്ഷണനിയമം) the total mass of the products equals that of the reactants.
- The products of burning are gases that escape from the open pan, so the balance does not weigh them. If they were collected and weighed, no mass would be missing.
Marking: 1 mark for (b).
📖 Revise: Ch 4 · Conservation of mass · Chapter 4 – Redox Reactions
Step-by-step solution
- In the Haber process iron (Fe) is the catalyst (ഉൽപ്രേരകം), at about 200 atm and 700 K.
- Vanadium pentoxide is the catalyst in the contact process; manganese dioxide speeds up the decomposition of hydrogen peroxide; amylase is an enzyme in saliva.
Marking: 1 mark for (c).
📖 Revise: Ch 5 · Catalysts – Haber and contact processes · Chapter 5 – Chemical Kinetics
Step-by-step solution
- Enamel paint is non-polar. Water is a polar solvent; turpentine is non-polar.
- A solute dissolves in a solvent of the same kind: like dissolves like (സമാനമായത് സമാനമായതിനെ ലയിപ്പിക്കും).
Marking: 1 mark for (b).
📖 Revise: Ch 6 · Organic solvents, like dissolves like · Chapter 6 – Solutions
Step-by-step solution
- The component present in the larger amount is the solvent (ലായകം).
- Gold is 916 g out of 1000 g, far more than silver and copper together (84 g), so gold is the solvent; silver and copper are the solutes.
Marking: 1 mark.
📖 Revise: Ch 6 · 916 gold box · Chapter 6 – Solutions
Step-by-step solution
- Saturated hydrocarbons are the alkanes, with only single bonds; their general formula is CnH2n+2.
- C4H10: n = 4, 2 × 4 + 2 = 10 ✔ – butane, an alkane. C3H4 and C2H2 fit CnH2n−2 (alkynes) and C2H4 fits CnH2n (an alkene) – all unsaturated.
Marking: 1 mark for (b).
📖 Revise: Ch 8 · Alkanes – C<sub>n</sub>H<sub>2n+2</sub> · Chapter 8 – Organic Chemistry
Step-by-step solution
- CH2=CH–CH3 has 3 carbon atoms → word root prop.
- It has a double bond → suffix -ene. Name: propene.
Marking: 1 mark.
📖 Revise: Ch 8 · Word roots and suffixes · Chapter 8 – Organic Chemistry
Step-by-step solution
- Given: mass number A = 19, neutrons = 10
- Formula: A = number of protons + number of neutrons, so atomic number Z (അറ്റോമിക നമ്പർ) = A − neutrons
- Substitution: Z = 19 − 10
- Answer: Z = 9. In a neutral atom, electrons = protons = 9.
- (b) Fill K first (2), then L: 9 = 2 + 7 → configuration (ഇലക്ട്രോൺ വിന്യാസം) 2, 7. The outermost shell (L) has 7 electrons. (X is fluorine.)
Marking: Atomic number ½, electrons ½, configuration ½, outermost electrons ½.
📖 Revise: Ch 1 · A − Z · Ch 1 · Electron configuration · Chapter 1 – Structure of the Atom
17Cl and 37
17Cl. Why would they be a problem in a table arranged by atomic mass, but not in the modern periodic table?
Step-by-step solution
- (a) Mendeleev’s periodic law (പീരിയോഡിക് നിയമം, 1869): the properties of elements are periodic functions of their atomic masses.
- Modern periodic law (ആധുനിക പീരിയോഡിക് നിയമം, Moseley): the chemical and physical properties of elements are periodic functions of their atomic numbers.
- (b) The two isotopes have different mass numbers (35 and 37), so by atomic mass they would need two different places – Mendeleev’s table had no separate places for isotopes.
- Both have the same atomic number, 17. The modern table is arranged by atomic number, so both share the one place of chlorine.
Marking: (a) each law ½; (b) reason 1 (½ for the problem by atomic mass, ½ for the same atomic number).
📖 Revise: Ch 2 · Mendeleev – merits and limitations · Ch 2 · Modern periodic law · Chapter 2 – Periodic Table
| Ion | Number of protons | Number of electrons | Electron configuration |
|---|---|---|---|
| Ca2+ | |||
| S2− |
Step-by-step solution
- Ca 2, 8, 8, 2 gives away its 2 outermost electrons → Ca2+ (a cation, കാറ്റയോൺ).
- S 2, 8, 6 takes 2 electrons → S2− (an anion, ആനയോൺ). Protons never change.
Ion Protons Electrons Configuration Ca2+ 20 20 − 2 = 18 2, 8, 8 S2− 16 16 + 2 = 18 2, 8, 8 - Both ions have the octet configuration 2, 8, 8 – the same as the noble gas argon.
Marking: Ca2+ row 1 (protons and electrons ½, configuration ½); S2− row 1 (same split).
📖 Revise: Ch 3 · Ions and their configurations · Ch 3 · Octet · Chapter 3 – Chemical Bonding
Step-by-step solution
- Given: Al = 27 u, O = 16 u; 4 Al atoms, 3 O2 molecules → 2 Al2O3
- Formula: total mass = sum of (number of particles × mass of one particle)
- Substitution: reactants = 4 × 27 + 3 × (2 × 16) = 108 + 96; products = 2 × (2 × 27 + 3 × 16) = 2 × (54 + 48) = 2 × 102
- Answer: reactants = 204 u, products = 204 u
- The masses are equal: the law of conservation of mass (മാസ് സംരക്ഷണനിയമം) – atoms are only rearranged.
Marking: Mass of reactants with working 1, mass of products with working ½, law ½.
📖 Revise: Ch 4 · Tables 4.1–4.2 · Chapter 4 – Redox Reactions
(i) A + B → AB (ii) AB → A + B (iii) A + BC → AC + B (iv) AB + CD → AD + CB
Step-by-step solution
- (i) Two substances join to give one product: combination (സംയോജന രാസപ്രവർത്തനം), e.g. CaO + H2O → Ca(OH)2.
- (ii) One compound breaks into two substances: decomposition (വിഘടന രാസപ്രവർത്തനം), e.g. CaCO3 → CaO + CO2↑.
- (iii) Element A takes the place of B in compound BC: displacement (ആദേശ രാസപ്രവർത്തനം), e.g. Zn + 2HCl → ZnCl2 + H2↑.
- (iv) Two compounds exchange their ions: double decomposition (ദ്വിവിഘടന രാസപ്രവർത്തനം), e.g. NaCl + AgNO3 → AgCl↓ + NaNO3.
Marking: ½ mark for each.
📖 Revise: Ch 5 · Combination and decomposition · Ch 5 · Double decomposition and displacement · Chapter 5 – Chemical Kinetics
Step-by-step solution
- Given: mass of solution = 250 g, mass percentage = 8 %
- Formula: mass percentage (മാസ് പെർസെന്റേജ്) = mass of solute ÷ mass of solution × 100, so mass of solute = mass % × mass of solution ÷ 100
- Substitution: mass of salt = 8 × 250 ÷ 100; mass of water = 250 − 20
- Answer: salt = 20 g, water = 230 g
Marking: Formula ½, mass of salt 1, mass of water ½.
📖 Revise: Ch 6 · Mass percentage · Chapter 6 – Solutions
Step-by-step solution
- (a) A white precipitate of barium carbonate forms: Na2CO3 + BaCl2 → BaCO3↓ + 2NaCl.
- (b) The precipitate dissolves with effervescence (bubbles): BaCO3 + 2HCl → BaCl2 + H2O + CO2↑.
- The gas is carbon dioxide. Passed into lime water (ചുണ്ണാമ്പുവെള്ളം) it turns the lime water milky. So the salt is a carbonate.
Marking: (a) white precipitate ½; (b) dissolves with effervescence ½, carbon dioxide ½, lime water turns milky ½.
📖 Revise: Ch 7 · Table 7.3 – test for carbonates · Chapter 7 – Non-metals
Step-by-step solution
- Given: alkane, n = 12; alkene, number of H = 16
- Formula: general formula (പൊതുവാക്യം) of alkanes CnH2n+2; of alkenes CnH2n
- Substitution: (a) H = 2 × 12 + 2; (b) 2n = 16, so n = 16 ÷ 2
- Answer: (a) 26 hydrogen atoms (C12H26); (b) 8 carbon atoms – C8H16
Marking: (a) formula ½, answer ½; (b) working ½, answer with formula ½.
📖 Revise: Ch 8 · C<sub>n</sub>H<sub>2n+2</sub> · Ch 8 · C<sub>n</sub>H<sub>2n</sub> · Chapter 8 – Organic Chemistry
Step-by-step solution
- Rules: period number = number of shells. Group 1 and 2: group number = number of outermost electrons. Groups 13–18: group number = outermost electrons + 10 (the ten groups 3–12 come in between).
- P (Z = 5): 2, 3 → 2 shells → period 2; 3 outermost electrons → 3 + 10 = group 13.
- Q (Z = 12): 2, 8, 2 → 3 shells → period 3; 2 outermost electrons → group 2.
- R (Z = 16): 2, 8, 6 → 3 shells → period 3; 6 outermost electrons → 6 + 10 = group 16.
- (P is boron, Q is magnesium, R is sulphur.)
Marking: For each element: configuration ½, period and group with the reason ½ (3 × 1).
📖 Revise: Ch 2 · Finding the group and period number · Chapter 2 – Periodic Table
Step-by-step solution
- (a) K: 2, 8, 8, 1 – it gives away its 1 outermost electron to reach an octet. O: 2, 6 – it takes 2 electrons to reach an octet.
- One oxygen atom needs 2 electrons but one potassium atom gives only 1, so two potassium atoms are needed.
- (b) Electron dot diagram (ഇലക്ട്രോൺ ഡോട്ട് ഡയഗ്രം) – only outermost electrons are drawn; × = electrons of potassium, • = electrons of oxygen:
- (c) K+: 2, 8, 8 (like argon); O2−: 2, 8 (like neon). Formula: K2O.
- The oppositely charged ions are held by electrostatic attraction – an ionic bond (അയോണിക ബന്ധനം). (Equation: 4K + O2 → 2K2O.)
Marking: (a) configurations and electrons lost/gained 1; (b) correct dot diagram with brackets and charges 1; (c) ion configurations ½, formula ½.
📖 Revise: Ch 3 · Electron dot diagrams · Ch 3 · Ionic compounds · Chapter 3 – Chemical Bonding
(a) Al + HCl → AlCl3 + H2
(b) C2H4 + O2 → CO2 + H2O (burning of ethene)
(c) Fe2O3 + H2 → Fe + H2O (hydrogen as a reducing agent)
Step-by-step solution
- Change only the numbers in front of the formulae (coefficients), never the subscripts. Count each kind of atom on both sides.
- (a) Cl: 3 in AlCl3, so put 6 in front of HCl for two AlCl3 → 2Al; then 6 H on the left → 3H2. 2Al + 6HCl → 2AlCl3 + 3H2
Atom Al H Cl Left side 2 6 6 Right side 2 6 6 - (b) 2 C → 2CO2; 4 H → 2H2O; O on the right = 4 + 2 = 6 → 3O2. C2H4 + 3O2 → 2CO2 + 2H2O
Atom C H O Left side 2 4 6 Right side 2 4 6 - (c) 2 Fe on the left → 2Fe; 3 O → 3H2O; then 6 H → 3H2. Fe2O3 + 3H2 → 2Fe + 3H2O
Atom Fe O H Left side 2 3 6 Right side 2 3 6
Marking: 1 mark for each balanced equation (½ if the atom count is shown but one coefficient is wrong).
📖 Revise: Ch 4 · Balancing equations · Chapter 4 – Redox Reactions
Step-by-step solution
- Given: sugar (solute, ലീനം) 60 g, water (solvent, ലായകം) 240 g
- Formula: mass percentage = mass of solute ÷ mass of solution × 100; mass of solution = solute + solvent
- Substitution: (a) 60 ÷ (60 + 240) × 100 = 60 ÷ 300 × 100
- Answer: (a) 20 %
- (b) 20 % means 20 g of sugar in every 100 g of syrup, so 50 g of syrup has 20 × 50 ÷ 100 = 10 g of sugar.
- (c) Mass of the drink = 50 + 150 = 200 g; mass percentage = 10 ÷ 200 × 100 = 5 %.
Marking: (a) formula ½, answer ½; (b) 1; (c) mass of the drink ½, answer ½.
📖 Revise: Ch 6 · Mass percentage · Chapter 6 – Solutions
Step-by-step solution
- (a) A – zinc (Zn) pieces; B – dilute hydrochloric acid (HCl).
- (b) Zn + 2HCl → ZnCl2 + H2↑. Zinc takes the place of hydrogen in HCl, so it is a displacement reaction (ആദേശ രാസപ്രവർത്തനം).
- (c) The gas burns with a “pop” sound (പോപ്പ് ശബ്ദം). This shows the gas is hydrogen.
Marking: (a) ½ + ½; (b) balanced equation ½, type ½; (c) observation ½, conclusion ½.
📖 Revise: Ch 7 · Laboratory preparation of hydrogen · Chapter 7 – Non-metals
Step-by-step solution
- Carbon has valency 4. For each carbon, H atoms = 4 − (number of bonds to other carbons; a double bond counts 2, a triple bond 3).
- P: condensed: CH3–CH2–CH2–CH2–CH3 → C5H12, alkane → pentane
- Q: condensed: CH2=CH–CH2–CH3 → C4H8, alkene → butene
- R: condensed: CH≡C–CH3 → C3H4, alkyne → propyne
- Check with the general formulas: pentane 2 × 5 + 2 = 12 H; butene 2 × 4 = 8 H; propyne 2 × 3 − 2 = 4 H.
Marking: For each compound: structure with every carbon having 4 bonds ½, molecular formula, family and name ½ (3 × 1).
📖 Revise: Ch 8 · Alkenes and alkynes · Ch 8 · IUPAC names · Chapter 8 – Organic Chemistry
(a) Name the electrodes P and Q. (b) When the tube contains air at normal pressure, no current flows through it even at a very high voltage. Why? What is done with R to make the discharge take place? (c) The glow at the ZnS coating stays the same whatever gas is taken in the tube and whatever metal the electrodes are made of. What did scientists conclude from this? Name the particles. (d) Goldstein used a cathode with holes in it in a similar tube and found rays coming out behind the cathode. Name these rays and give one way in which they differ from the rays from P.
Step-by-step solution
- (a) P is joined to the negative terminal – the cathode (കാഥോഡ്). Q is joined to the positive terminal – the anode, here a perforated anode (സുഷിരങ്ങളുള്ള ആനോഡ്).
- (b) Air at normal pressure is an insulator (വൈദ്യുതരോധി), so no current flows. The air is pumped out through R with a vacuum pump (നിർവാത പമ്പ്) step by step until the pressure is very low; then the electric discharge takes place.
- (c) The cathode rays (കാഥോഡ് രശ്മികൾ) do not depend on the gas or the metal, so the particles in them must be present in all matter. These particles are electrons.
- (d) Canal rays (കനാൽ രശ്മികൾ), also called anode rays. Difference (any one): canal rays are positively charged while cathode rays are negative; the nature of canal rays depends on the gas (hydrogen gives the lightest particles – protons), but cathode rays do not.
Marking: (a) ½ + ½; (b) insulator ½, reduce the pressure through R ½; (c) present in all matter ½, electrons ½; (d) name ½, difference ½.
📖 Revise: Ch 1 · Discharge tube and cathode rays · Ch 1 · Canal rays · Chapter 1 – Structure of the Atom
(a) Write the atomic number, the mass number and the electron configuration of X. (b) Find the period number and the group number of X. Give the reasons. (c) Name the family of X. Name one other element (Z ≤ 20) with similar chemical properties and say why they are similar. (d) Element Y has one proton fewer than X. Write the configuration of Y. Are X and Y in the same period or in the same group?
Step-by-step solution
- (a) Protons = 20 → atomic number 20. Mass number = 20 + 20 = 40. Electrons in the shells: 2, 8, 8, 2. (X is calcium.)
- (b) 4 shells → period 4 (period number = number of shells). 2 outermost electrons → group 2 (for groups 1 and 2, group number = number of outermost electrons).
- (c) Group 2 is the family of alkaline earth metals (ആൽക്കലൈൻ എർത്ത് ലോഹങ്ങൾ). Magnesium (2, 8, 2) or beryllium (2, 2) – they also have 2 outermost electrons (ബാഹ്യതമ ഇലക്ട്രോണുകൾ), and chemical properties depend on the outermost electrons.
- (d) Y has 19 protons → 19 electrons → 2, 8, 8, 1 (potassium). Y also has 4 shells, so X and Y are in the same period (period 4); Y is in group 1, X in group 2.
Marking: (a) Z and A ½, configuration ½; (b) period with reason ½, group with reason ½; (c) family ½, element with reason ½; (d) configuration ½, same period ½.
📖 Revise: Ch 2 · Group and period number · Ch 2 · Families · Chapter 2 – Periodic Table
(a) CaCO3 → CaO + CO2↑ – name the type of this reaction. (b) CaO + H2O → Ca(OH)2 – name the type of reaction and write one sign that shows a chemical change. (c) Write the equation for the reaction of iron with copper sulphate solution. Name its type and say what Raghavan would see in the bucket. (d) When the two are mixed: CuSO4 + Ca(OH)2 → Cu(OH)2↓ + CaSO4. Name the type of this reaction and give the reason.
Step-by-step solution
- (a) One compound breaks into two substances: decomposition – heating is used, so it is a thermal decomposition (താപീയ വിഘടനം).
- (b) Two substances combine to give one compound: combination. Sign: the mixture becomes very hot – heat is given out (an exothermic reaction, താപമോചക പ്രവർത്തനം).
- (c) Fe + CuSO4 → FeSO4 + Cu – iron replaces copper in the compound: displacement. A reddish-brown coat of copper appears on the iron and the blue colour of the solution fades. (The bucket is eaten away and the copper sulphate is wasted.)
- (d) Double decomposition (ദ്വിവിഘടന രാസപ്രവർത്തനം): the two compounds exchange their ions – Cu2+ joins OH−, and Ca2+ joins SO42−, forming two new compounds.
Marking: Each part 1 mark: (a) type 1; (b) type ½, sign ½; (c) equation and type ½, observation ½; (d) type ½, reason ½.
📖 Revise: Ch 5 · Combination and decomposition · Ch 5 · Displacement and double decomposition · Chapter 5 – Chemical Kinetics
(a) What is meant by calorific value? Which fuel in the chart has the highest calorific value? (b) Find the heat released when 5 g of hydrogen burns completely. (c) What mass of carbon monoxide must burn completely to give the same amount of heat? (d) Write one merit and one limitation of hydrogen as a fuel.
Step-by-step solution
- (a) Calorific value (കലോറിക മൂല്യം) is the heat energy released when unit mass of a fuel burns completely (kJ/g). Hydrogen has the highest value, 143 kJ/g.
- Given: hydrogen 143 kJ/g, carbon monoxide 10 kJ/g; mass of hydrogen 5 g
- Formula: heat released = mass × calorific value; mass = heat ÷ calorific value
- Substitution: (b) heat = 5 × 143; (c) mass of CO = 715 ÷ 10
- Answer: (b) 715 kJ; (c) 71.5 g of carbon monoxide – more than 14 times the mass of hydrogen.
- (d) Merit: very high calorific value, and burning it gives only water (2H2 + O2 → 2H2O), so there is little pollution. Limitation: it burns explosively, and it is difficult to store and transport.
Marking: (a) definition ½, hydrogen ½; (b) 1; (c) 1; (d) merit ½, limitation ½.
📖 Revise: Ch 7 · Calorific value – Fig 7.2 · Chapter 7 – Non-metals
Question numbers by chapter
| Chapter | A (1) | B (2) | C (3) | D (4) | Total |
|---|---|---|---|---|---|
| 1. Structure of the Atom | 1 | 11 | – | 25 | 7 |
| 2. Periodic Table | – | 12 | 19 | 26 | 9 |
| 3. Chemical Bonding | 2, 3 | 13 | 20 | – | 7 |
| 4. Redox Reactions | 4, 5 | 14 | 21 | – | 7 |
| 5. Chemical Kinetics | 6 | 15 | – | 27 | 7 |
| 6. Solutions | 7, 8 | 16 | 22 | – | 7 |
| 7. Non-metals | – | 17 | 23 | 28 | 9 |
| 8. Organic Chemistry | 9, 10 | 18 | 24 | – | 7 |
| Total | 10 | 16 | 18 | 16 | 60 |
Score to grade
Kerala grading scale: A+ 54–60 (90 %+), A 48–53, B+ 42–47, B 36–41, C+ 30–35, C 24–29, D+ 18–23, D 12–17, E below 12. For every question the student lost marks on, the linked guide page explains the idea again.